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High-pressure (HP) structural and magnetic properties of a magnetic coordination polymer {[NiII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (Ni2Nb) are presented, discussed and compared with its two previously reported analogs {[MnII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (Mn2Nb) and {[FeII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (Fe2Nb). Ni2Nb shows a significant decrease of the long-range ferromagnetic ordering under high pressure when compared to Mn2Nb, where the pressure enhances the Tc (magnetic ordering temperature), or to Fe2Nb exhibiting a pressure-induced spin crossover. The different HP magnetic responses of the three compounds were rationalized and correlated with the structural models as determined by single-crystal X-ray diffraction.

magnetochemistry

How to Quench Ferromagnetic Ordering in a CN-Bridged Ni(II)-Nb(IV) Molecular Magnet? A Combined High-Pressure Single-Crystal X-Ray Diffraction and Magnetic Study