English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The furan-functionalised 1,2,4-triazole ligand furanylidene-4H-1,2,4-triazol-4-amine (furtrz) has been incorporated into the trinuclear complex Fe3(furtrz)6(ptol)2(MeOH)4]·4(ptol)·4(MeOH) (ptol = p-tolylsulfonate) composed of μ1,2-triazole bridges between iron(II) sites, as per one-dimensional chain materials, and terminally coordinated ptol anions and methanol molecules. Magnetic susceptibility measurements reveal a gradual single-step spin crossover (SCO) behavior of one third of the iron(II) sites per trinuclear unit. Single-crystal X-ray diffraction below the transition (90 K) shows the central iron(II) sites undergo a HS to LS transition and the peripheral ones remain HS (HS = high spin; LS = low spin). This is a rare example of a cationic trinuclear SCO material where the discrete unit includes bound anions

magnetochemistry

Structure and Magnetic Properties of the Spin Crossover Linear Trinuclear Complex [Fe3(furtrz)6(ptol)2(MeOH)4]·4(ptol)·4(MeOH) (furtrz: furanylidene-4H-1,2,4-triazol-4-amine ptol: p-tolylsulfonate)