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We set out to study the use of a series of ruthenocenes as possible and promising sources for ruthenium and/or ruthenium oxide film formation.The thermal stability of a series of ruthenocenes, including ( η  5 -C 5 H 4 R)( η  5 -C 5 H 4 R´)Ru ( 1) , R = R´ = H ( 3) , R = H, R´ = CH 2 NMe 2  ( 5) , R = H, R´= C(O)Me ( 6) , R = R´ = C(O)Me ( 7) , R = H, R´ = C(O)(CH 2 ) 3 CO 2 H ( 8) , R = H, R´ = C(O)(CH 2 ) 2 CO 2 H ( 9) , R = H, R´ = C(O)(CH 2 ) 3 CO 2 Me ( 10) , R = H, R´= C(O)(CH 2 ) 2 CO 2 Me ( 11),  R = R´ = SiMe 3 ), ( η  5 -C 4 H 3 O-2,4-Me 2 ) 2 Ru ( 2) , and ( η  5 -C 5 H 5 -2,4-Me 2 ) 2 Ru ( 4)  was studied by thermogravimetry. From these studies, it could be concluded that  1 – 4, 6  and  9–11  are the most thermally stable molecules. The sublimation pressure of these sandwich compounds was measured using a Knudsen cell. Among these, the compound  11  shows the highest vapor pressure.

Thermal Stability and Sublimation Pressures of Some Ruthenocene Compounds