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The paper presents a comparison of the results of the corrosion resistance for three Fe-B-Co-Si-based newly developed alloys with the addition of Nb and V. The corrosion performance differences and microstructure variations were systematically studied using scanning electron microscope, electric corrosion equipment, X-ray diffractometer, and differential calorimeter. It has been shown that each alloying addition increased the corrosion resistance. The highest corrosion resistance obtained by potentiodynamic polarization was found for the alloy with both Nb and V addons (Fe 57 Co 10 B 20 Si 5 Nb 4 V 4 ) and lowest in the case of the basic four-element Fe 62 Co 15 B 14 Si 9 material. This shows that the proper choice of additions is of significant influence on the final performance of the alloy and allows tailoring of the material for specific applications.

Influence of the Nb and V Addition on the Microstructure and Corrosion Resistance of the Fe-B-Co-Si Alloy