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Phase formation and microstructure of (Nd 1-2x Ce x Y x ) 14.5 Fe 79.3 B 6.2 (x = 0.05, 0.10, 0.15, 0.20, 0.25) alloys were studied experimentally. The results reveal that (Nd 1-2x Ce x Y x ) 14.5 Fe 79.3 B 6.2 annealed alloys show (NdCeY) 2 Fe 14 B phase with the tetragonal Nd 2 Fe 14 B-typed structure (space group P4 2 /mnm) and rich-RE (α-Nd) phase, while (Nd 1-2x Ce x Y x ) 14.5 Fe 79.3 B 6.2 ribbons prepared by melt-spun technology are composed of (NdCeY) 2 Fe 14 B phase, α-Nd phase and α-Fe phase, except for the ribbon with x = 0.25, which consists of additional CeFe 2 phase. On the other hand, magnetic properties of (Nd 1-2x Ce x Y x ) 14.5 Fe 79.3 B 6.2 melt-spun ribbons were measured by a vibrating sample magnetometer (VSM). The measured results show that the remanence (B r ) and the coercivity (H cj ) of the melt-spun ribbons decrease with the increase of Ce and Y substitutions, while the maximum magnetic energy product ((BH) max ) of the ribbons decreases and then increases. The tendency of magnetic properties of the ribbons could result from the co-substitution of Ce and Y for Nd in Nd 2 Fe 14 B phase and different phase constitutions. It was found that the H cj of the ribbon with x = 0.20 is relatively high to be 9.01 kOe, while the (BH) max of the ribbon with x = 0.25 still reaches to be 9.06 MGOe. It suggests that magnetic properties of Nd-Fe-B ribbons with Ce and Y co-substitution could be tunable through alloy composition and phase formation to fabricate novel Nd-Fe-B magnets with low costs and high performance.

Phase Formation, Microstructure, and Magnetic Properties of Nd14.5Fe79.3B6.2 Melt-Spun Ribbons with Different Ce and Y Substitutions