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The derivatives 5,7-dimethyl[1,3,4]thiadiazolo[3,2- a ]pyrimidin-4-ium-2-thiolate ( 1 ) and 7-methyl-5-phenyl[1,3,4]thiadiazolo[3,2- a ]pyrimidin-4-ium-2-thiolate ( 2 ) were fully characterized by single-crystal X-ray diffraction. Their supramolecular structure is built through both π-π stacking and C=S-π interactions for both compounds. The embedment of the tested compounds into Fe 3 O 4 @C 18 core-shell nanocoatings increased the protection degree against Candida albicans biofilms on the catheter surface, suggesting that these bioactive nanocoatings could be further developed as non-cytotoxic strategies for fighting biofilm-associated fungal infections.

Anti-biofilm Fe3O4@C18-[1,3,4]thiadiazolo[3,2-a]pyrimidin-4-ium-2-thiolate Derivative Core-shell Nanocoatings