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The electrochemical redox behavior of three trinuclear Ni(II) complexes [Ni 3 (abb) 3 (H 2 O) 3 (µ-ttc)](ClO 4 ) 3 ( 1 ), [Ni 3 (tebb) 3 (H 2 O) 3 (µ-ttc)](ClO 4 ) 3 ·H 2 O ( 2 ), and [Ni 3 (pmdien) 3 (µ-ttc)](ClO 4 ) 3 ( 3 ), where abb = 1-(1H-benzimidazol-2-yl)-N-(1H-benzimidazol-2-ylmethyl)methan-amine, ttcH 3 = trithiocyanuric acid, tebb = 2-[2-[2-(1H-benzimidazol-2-yl)ethylsulfanyl]ethyl]-1H-benzimidazole, and pmdien = N,N,N',N″,N″-pentamethyldiethylenetriamine is reported. Cyclic voltammetry (CV) was applied for the study of the electrochemical behavior of these compounds. The results confirmed the presence of ttc and nickel in oxidation state +2 in the synthesized complexes. Moreover, the antibacterial properties and cytotoxic activity of complex 3 was investigated. All the complexes show antibacterial activity against Staphylococcus aureus and Escherichia coli to different extents. The cytotoxic activity of complex 3 and ttcNa 3 were studied on G-361, HOS, K-562, and MCF7 cancer cell lines. It was found out that complex 3 possesses the cytotoxic activity against the tested cell lines, whereas ttcNa 3 did not show any cytotoxic activity.

An Investigation on the Electrochemical Behavior and Antibacterial and Cytotoxic Activity of Nickel Trithiocyanurate Complexes