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In this work, we report a feasible fabrication of NiCo 2 S 4 nanotree-like structures grown from the Ni nanoparticle (NP)-doped reduced graphene oxides (Ni-rGO) by a simple hydrothermal method. It is found that the presence of Ni NPs on the surface of the rGOs initiates growth of the NiCo 2 S 4 nanotree flocks with enhanced interfacial compatibility, providing excellent cyclic stability and rate performance. The resulting NiCo 2 S 4 /Ni-rGO nanocomposites exhibit a superior rate performance, demonstrating 91.6% capacity retention even after 10,000 cycles of charge/discharge tests.

NiCo2S4 Nanotrees Directly Grown on the Nickel NP-Doped Reduced Graphene Oxides for Efficient Supercapacitors