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In order to improve the strength of polyvinyl alcohol (PVA)/xylan composite films and endow them with ultraviolet (UV) shielding ability, TiO₂-KH550 nanoparticles was synthesized and added into the PVA/xylan matrix. The TiO₂-KH550 nanoparticle dispersed well in the 0.04% sodium hexametaphosphate (SHMP) solution under ultrasonic and stirring treatments. Investigations on the properties of the films showed that TiO₂-KH550 had the positive impact on improving the strength, moisture, and oxygen barrier properties of the composite films. The maximum tensile strength (27.3 MPa), the minimum water vapor permeability (2.75 × 10 -11 g·m -1 ·s -1 ·Pa -1 ), and oxygen permeability (4.013 cm³·m -2 ·24 h -1 ·0.1MPa -1 ) were obtained under the addition of 1.5% TiO₂-KH550. The tensile strength of TiO₂-KH550 reinforced composite film was increased by 70% than that of the pure PVA/xylan composite film, and the water vapor and oxygen permeability were decreased by 31% and 41%, respectively. Moreover, the UV transmittance of the film at the wavelength of 400 nm was almost zero when adding ≈1.5~2.5% (weight ratio, based on the total weight of PVA and xylan) of TiO₂-KH550, which indicated the PVA/xylan composite films were endowed with an excellent UV light shielding ability.

TiO2-KH550 Nanoparticle-Reinforced PVA/xylan Composite Films with Multifunctional Properties