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In this paper, the influence of the extra solid phase reaction on the interface structure and mechanical properties of titanium carbonitride-based cermets were investigated. The extra solid phase reaction in the preparation process of cermets could induce the formation of a core/rim/binder interface with the coherent structure and reinforce the interface bonding strength in cermets. The existence of a coherent structure interface can inhibit crack spread and improve the toughness and abrasion resistance of titanium carbonitride-based cermets significantly. Cermets can exhibit the high hardness Rockwell Hardness A (HRA) 92.3, fracture toughness of 11.6 MPa·m 1/2 , and transverse rupture strength of 2810 MPa.

Enhanced Interface Structure and Properties of Titanium Carbonitride-Based Cermets with the Extra Solid Phase Reaction