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The in situ synthesis of silver nanoparticles (AgNPs) was performed using resorcinol and agar to produce agar-based antioxidant and antimicrobial films. AgNPs were regularly dispersed on the film matrix, and their presence improved the thermal stability of films. Additionally, the addition of AgNPs slightly increased the agar-based film’s tensile strength (~10%), hydrophobicity (~40%), and water vapor barrier properties (~20%) at 1.5 wt% of AgNP concentration. The resorcinol also imparted UV-barrier and antioxidant activity to the agar-based film. In particular, the agar-based film containing a higher quantity of AgNPs (&gt;1.0 wt%) was highly effective against the foodborne pathogenic bacteria L. monocytogenes and E. coli. Therefore, agar-based composite films with improved physicochemical and functional properties may be promising for active packaging.

A Facile In Situ Synthesis of Resorcinol-Mediated Silver Nanoparticles and the Fabrication of Agar-Based Functional Nanocomposite Films