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Polypropylene/polylactic acid (PP/PLA) blend (10–40% of PLA) and PP/PLA/MWCNTs nanocomposites (0.5, 1, and 2 wt% of MWCNTs) were prepared via melt compounding. Scanning electron microscopy revealed a co-continuous PLA phase in the PP/PLA blends with high PLA content. Moreover, the addition of 2 wt% multi-walled carbon nanotubes (MWCNTs) increased the tensile modulus and tensile strength of the PP/PLA40% by 60% and 95%, respectively. A conductive network was found with the addition of 2 wt% MWCNTs, where the electrical conductivity of the PP/PLA increased by nine orders of magnitude. At 2 wt% MWCNTs, a solid network within the composite was characterized by rheological assessment, where the composite turned from nonterminal to terminal behavior. Soil burial testing of the PP/PLA blend within 30 days in natural humus compost soil featured suitable biodegradation, which indicates the PP/PLA blend is as an appropriate candidate for food packing applications.

The Role of Multiwalled Carbon Nanotubes in the Mechanical, Thermal, Rheological, and Electrical Properties of PP/PLA/MWCNTs Nanocomposites