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The suitability of sewage-sludge derived washing agents (SS_WAs) (dissolved organic matter DOM; humic-like substances HLS; soluble humic substances SHS), was assessed for removing Cd from highly contaminated (300 mg/kg) sandy clay loam and clay. The soils were remediated via column flushing at two flow rates, 0.5 and 1.0 mL/min. The stability of the flow velocity (FV) depended on the type of SS_WA and decreased in the following order: DOM &gt; HLS &gt; SHS. Cd was most effectively removed during the first hours of flushing, and the process proceeded with a first-order kinetics. The overall process efficiency was higher at flow rate of 1.0 mL/min than at 0.5 mL/min and ranged from 65.7 (SHS) to 75.5% (DOM) for the sandy clay loam and from 64.7% (SHS) to 67.8% (DOM) for the clay. However, all SS_WAs at both flow rates removed the most mobile Cd fraction (F1) with an efficiency above 90%. Flushing improved soil characteristics in terms of the content of organic matter, humic substances and nutrients. Among all SS_WAs, DOM was the most suitable for remediation of highly Cd-contaminated soils due to high efficiency of Cd removal, the high stability of its FV during flushing and the simple manner of DOM recovery from sewage sludge.

Flushing of Soils Highly Contaminated with Cd Using Various Washing Agents Derived from Sewage Sludge