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A hybrid H2–air kinetic scheme of 11 species and 15 reactions is developed, which is capable of simulating the high-temperature air reaction flows and H2–O2 combustion flows respectively or simultaneously. Based on the Gupta scheme, the mole fraction varying with a Mach number at specific conditions is analyzed, and the weakly-ionized 7-species 7-reaction scheme is selected. The effect of nitrogenous species on the H2–O2 combustion is analyzed by a zero-dimensional simulation of steady-state and unsteady-state combustion under specified conditions, and the selected dominant nitrogenous reaction N + OH = NO + H is distinguished by the production rate of the nitrogenous species. The thermodynamic properties are verified by comparison using the NIST–JANAF database. The reaction rate coefficients of the dominant reaction of the hybrid kinetic scheme distinguished by a sensitivity analysis are corrected. The proposed kinetic scheme is validated by a zero-dimensional calculation of the ignition delay time and two-dimensional computational fluid dynamics (CFD) simulation with finite-rate chemistry on the shock-induced sub-detonative and super-detonative combustion. The ignition delay time of the hybrid kinetic scheme is almost in the middle between the Shang scheme and Jachimowski scheme, and all the calculated ignition delay times are acceptably greater than the experiments due to the errors of the experiments and numerical models. The clearly captured bow shock wave and combustion front using the hybrid kinetic scheme and Shang scheme are almost the same, which is strongly consistent with the schlieren image. In addition, a good agreement of the flow characteristics and mass fraction of the species along the stagnation line is also obtained, which indicates the accuracy and reasonableness of the hybrid kinetic scheme to simulate hybrid H2–air reactive flows.

Modeling of a Reduced Hybrid H2–Air Kinetic Scheme Integrating the Effect of Hypersonic Reactive Air with Supersonic Combustion