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In this study, the process of the solidification of a PCM (phase change material) liquid in an annular space was analytically investigated with the use of a simplified quasi-steady-state model. This model described the phase change phenomenon with the cylindrical solidification front and with the solidification liquid overheated above the solidification temperature. One of the important novelties of the applied model was the determination of the coefficient of the heat transfer between the liquid and the solidified layer on the solidification surface, which was calculated as a function of the location of the solidification front. A method for calculating the variable coefficient of heat transfer on the surface of the solidification front during the solidification process is presented. The contact layer between the cold wall and the solidified layer was incorporated into the model and played an important role. The theoretical analytical method describing the solidification process based on the quasi-steady model was used in the study. Moreover, the main problem considered in this work could be reduced to a conjugate system of differential equations, allowing it to be solved numerically. From this perspective, the influence of various dimensionless parameters on the solidification process could be clearly seen. The obtained numerical results are presented in graphical form. The results of the theoretical research were compared with the experimental research of one of the author’s earlier works and they showed a significant agreement. Finally, the simple analytical approach presented in this work can be used for designing annular heat accumulators.

Analytical Study of the Solidification of a Phase Change Material in an Annular Space