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Reaction of different substituted 2-chloro-4-methylquinolines with sodium azide changed the direction to substituted tetrazolo[1,5-a]quinolines instead corresponding 2-azido-4-methylquinolines. Required 2-chloro-derivatives were obtained from substituted 4-methylquinolin-2(1H)-ones, which were synthesized by ring closing corresponding (un)substituted acetoacetanildes in the presence of ionic liquid [Bmim]OH. The structures of obtained compounds have been confirmed by using spectroscopic methods (IR, NMR and MS).

proceedings of the 21st international electronic conference on synthetic organic chemistry

&lt;strong&gt;STUDY ON REACTION OF &lt;span&gt;SUBSTITUTED 4-METHYLQUINOLIN-2(1&lt;em&gt;H&lt;/em&gt;)-ONES&lt;/span&gt;&lt;/strong&gt;&lt;strong&gt; WITH SODIUM AZIDE&lt;/strong&gt;