English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

1,3-alkyl-imidazolium-based ionic liquids show a wide range of applications from use as a "designer solvent", in catalysis1-3 up to material science4-6. The interaction between cation and anion can be investigated by analyzing the crystal structure.7 In our work, we synthesized various 1,3-functionalized imidazolium and choline based Ils for the use as drying agent in sorption systems. Here especially substances with organic anion such as acetate, lactate and formate were quiet interesting because they expected, among other beneficial properties, a low melting point and a strongly pronounced hygroscopic behavior. However, the purification of the synthesized compounds showed a number of previously unknown crystal structures which offers interesting thermodynamic aspects, as well as the interaction of cations and anions could be examined. In addition, the crystal structure data provided the molecular volume of the ions, which is used to predict thermodynamic aspects.    P. Wasserscheid and W. Keim, Angew. Chem. Int. Ed., 2000, 39, 3772-3789.  S. Peleteiro, S. Rivas, J. L. Alonso, V. Santos and J. C. Parajo, Bioresour. Technol., 2016, 202, 181-191.  H.-P. Steinruck and P. Wasserscheid, Catal. Lett., 2014, 145, 380-397.  Y. Chen, Y. Cao and T. Mu, Chem. Eng. Technol., 2014, 37, 527-534.  P. Wasserscheid and M. Seiler, ChemSusChem, 2011, 4, 459-463.  S. Herrmann, M. Kostrzewa, A. Wierschem and C. Streb, Angew. Chem., 2014, 126, 13814-13817.  T. Brunig, K. Krekic, C. Bruhn and R. Pietschnig, Chem. Eur. J., 2016, DOI: 10.1002/chem.201602723, n/a-n/a.

Investigations of structure property relationships of highly hygroscopic Imidazolium and Choline based ILs for the prediction of thermodynamic trends