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We report on the crystal growth of rare-earth pyrosilicates, R 2Si 2O 7 for R = Yb and Er using the optical floating zone method. The grown crystals comprise members from the family of pyrosilicates where the rare-earth atoms form a distorted honeycomb lattice. C-Yb 2Si 2O 7 is a quantum dimer magnet with field-induced long range magnetic order, while D-Er 2Si 2O 7 is an Ising-type antiferromagnet. Both growths resulted in multi-crystal boules, with cracks forming between the different crystal orientations. The Yb 2Si 2O 7 crystals form the C-type rare-earth pyrosilicate structure with space group C 2 / m and are colorless and transparent or milky white, whereas the Er-variant is D-type, P 2 1 / b , and has a pink hue originating from Er 3 +. The crystal structures of the grown single crystals were confirmed through a Rietveld analysis of the powder X-ray diffraction patterns from pulverized crystals. The specific heat of both C-Yb 2Si 2O 7 and D-Er 2Si 2O 7 measured down to 50 mK indicated a phase transition at T N ≈ 1.8 K for D-Er 2Si 2O 7 and a broad Schottky-type feature with a sharp anomaly at 250 mK in an applied magnetic field of 0.8T along the c-axis in the case of C-Yb 2Si 2O 7 .

Crystal Growth of Quantum Magnets in the Rare-Earth Pyrosilicate Family R2Si2O7 (R = Yb, Er) Using the Optical Floating Zone Method