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Three mononuclear 2-picolylamine-containing zinc(III) complexes viz [(2-PA)2ZnCl]2(ZnCl4)] (Zn1), [(2-PA)2Zn(H2O)](NO3)2] (Zn2) and [Zn(2-PA)2(OH)]NO3] (Zn3) were synthesized and fully characterized. Spectral and X-ray structural characteristics showed that the Zn1 complex has a square-pyramidal coordination environment around a zinc(II) core. The hydroxide complex Zn3 was non-covalently functionalized with few layers of graphene oxide (GO) sheets, formed by exfoliation of GO in water. The resulting Zn3/GO hybrid material was characterized by FT-IR, TGA-DSC, SEM-EDX and X-ray powder diffraction. The way of interaction of Zn3 with GO has been established through density functional theory (DFT) calculations. Both experimental and theoretical findings indicate that, on the surface of GO, the complex Zn3 forms a complete double-sided adsorption layer. Zn3 and its hybrid form Zn3/GO have been individually investigated as electrocatalysts for the hydrogen evolution reaction. The hybrid heterogenized form Zn3/GO was supported on glassy carbon (GC) with variable loading densities of Zn3 (0.2, 0.4 and 0.8 mg cm−2) to form electrodes. These electrodes have been tested as molecular electrocatalysts for the hydrogen evolution reaction (HER) using linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) in 0.1 M KOH. Results showed that both GC-Zn3 and GC-Zn3/GO catalysts for the HER are highly active, and with increase of the catalyst’s loading density, this catalytic activity enhances. The high catalytic activity of HER with a low onset potential of −140 mV vs. RHE and a high exchange current density of 0.22 mA cm−2 is achieved with the highest loading density of Zn3 (0.8 mg cm−2). To achieve a current density of 10 mA cm−2, an overpotential of 240 mV was needed.

Non-Covalent Functionalization of Graphene Oxide-Supported 2-Picolyamine-Based Zinc(II) Complexes as Novel Electrocatalysts for Hydrogen Production