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The use of titania-based composite materials in the field of heterogeneous catalysis and photocatalysis has a long and rich history. Hybrid structures combining titania nanoparticles with clay minerals have been extensively investigated for nearly four decades. The attractiveness of clay minerals as components of functional materials stems primarily from their compositional versatility and the possibility of using silicate lamellae as prefabricated building blocks ready to be fitted into the desired nanoconstruction. This review focuses on the evolution over the years of synthetic strategies employed for the manufacturing of titania–clay mineral composites with particular attention to the role of the adopted preparative approach in shaping the physical and chemical characteristics of the materials and enabling, ultimately, tuning of their catalytic and/or photocatalytic performance.

Titania-Clay Mineral Composites for Environmental Catalysis and Photocatalysis