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Molybdenum-zeolite catalysts always suffer from severe carbon deposition and rapid deactivation in the methane dehydroaromatization (MDA) process. Herein, we present a strategy that controls spatial distance between Mo species and HMCM-22 zeolite over Mo/HMCM-22 catalysts, to inhibit the severe carbon deposition. Our characterization analyses demonstrate that the Mo/HMCM-22 catalysts possess the same active components, but the spatial distance plays a key role in determining product selectivity in the MDA process. The MDA performance reveals that Mo/HMCM-22-MM (mechanical milling) catalyst, with a medium spatial distance between Mo species and HMCM-22 zeolite, significantly inhibits carbon deposition and produces high selectivity to benzene. This work shows that spatial distance between molybdenum and zeolite is an important property for suppressing carbon deposition and improving benzene selectivity in MDA process.

Resistance against Carbon Deposition via Controlling Spatial Distance of Catalytic Components in Methane Dehydroaromatization