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Photodegradation is a key process impacting the lifetime of oxalate in the atmosphere, but few studies investigated this process in the field due to the complex mixing and sources of oxalate. Oxalate-containing particles were measured via single-particle aerosol mass spectrometry at coastal and suburban sites in Qingdao, a coastal city in North China in the summer of 2016. The mixing state and influence of different ambient conditions on the source and photodegradation of oxalate were investigated. Generally, 6.3% and 12.3% of the total particles (by number) contained oxalate at coastal and suburban sites, respectively. Twelve major types of oxalate-containing particles were identified, and they were classified into three groups. Biomass burning (BB)-related oxalate–K and oxalate–carbonaceous particles were the dominant groups, respectively, accounting for 68.9% and 13.6% at the coastal site and 72.0% and 16.8% at the suburban site. Oxalate–Heavy metals (HM)-related particles represented 14.6% and 9.3% of the oxalate particles at coastal and suburban sites, respectively, which were mainly from industrial emissions (Cu-rich, Fe-rich, Pb-rich), BB (Zn-rich), and residual fuel oil combustion (V-rich). The peak area of oxalate at the coastal site decreased immediately after sunrise, while it increased during the daytime at the suburban site. However, the oxalate peak area of Fe-rich particles at both sites decreased after sunrise, indicating that iron plays an important role in oxalate degradation in both environments. The decay rates (k) of Fe-rich and BB-Fe particles at the coastal site (−0.978 and −0.859 h−1, respectively), were greater than those at the suburban site (−0.512 and −0.178 h−1, respectively), owing to the high-water content of particles and fewer oxalate precursors. The estimated k values of oxalate peak area for different ambient conditions were in the same order of magnitude, which can help establish or validate the future atmospheric models.

atmosphere

Influence of Ambient Atmospheric Environments on the Mixing State and Source of Oxalate-Containing Particles at Coastal and Suburban Sites in North China