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Visibility is important because it influences transportation safety. This study examined the relationships among sea–land breezes, relative humidity (RH), and the urban heat island (UHI) effect. The study also sought to understand how the synergistic effects of fine particulate matter (PM2.5) and RH influence visibility. Hourly meteorological, PM2.5 concentration, and visibility data from 2016 to 2019 were obtained from government-owned stations. This study used quadratic equations, exponential functions, and multi-regression models, along with a comparison test, to analyse the relationships between these variables. While sea breezes alone cannot explain the presence of PM2.5, UHI circulation coupled with sea breezes during winter can promote the accumulation of PM2.5. The synergistic effects of RH, PM2,5, and aerosol hygroscopicity exist in synoptic patterns type I and type III. PM2.5 was negatively correlated with visibility in the winter, when the RH was 67–95% and the continental cold high-pressure (CCHP) system was over the Asian continent (type I), or when the RH was 49–89% and the CCHP had moved eastward, with its centre located beyond 125° E (type III). The synergistic predictor variable PM2.5×RH was more important than PM2.5 and RH individually in explaining the variation in visibility.

Poor Visibility in Winter Due to Synergistic Effect Related to Fine Particulate Matter and Relative Humidity in the Taipei Metropolis, Taiwan