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State of charge (SOC) estimation is generally acknowledged to be one of the most important functions of the battery management system (BMS) and is thus widely studied in academia and industry. Based on an accurate SOC estimation, the BMS can optimize energy efficiency and protect the battery from being over-charged or over-discharged. The accurate online estimation of the SOC is studied in this paper. First, it is proved that the second-order resistance capacitance (RC) model is the most suitable equivalent circuit model compared with the Thevenin and multi-order models. The second-order RC equivalent circuit model is established, and the model parameters are identified. Second, the reasonable optimization of model parameters is studied, and a reasonable optimization method is proposed to improve the accuracy of SOC estimation. Finally, the SOC is estimated online based on the adaptive unscented Kalman filter (AUKF) with optimized model parameters, and the results are compared with the results of an estimation based on pre-optimization model parameters. Simulation experiments show that, without affecting the convergence of the initial error of the AUKF, the model after parameter optimization has a higher online SOC estimation accuracy.

SOC Estimation with an Adaptive Unscented Kalman Filter Based on Model Parameter Optimization