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The work focused on the layered perovskite-related materials as the potential electrolytic components of such devices as proton conducting solid oxide fuel cells for the area of clean energy. The two-layered perovskite BaLa2In2O7 with the Ruddlesden–Popper structure was investigated as a protonic conductor for the first time. The role of increasing the amount of perovskite blocks in the layered structure on the ionic transport was investigated. It was shown that layered perovskites BaLanInnO3n+1 (n = 1, 2) demonstrate nearly pure protonic conductivity below 350 °C.

Protonic Transport in Layered Perovskites BaLanInnO3n+1 (n = 1, 2) with Ruddlesden-Popper Structure