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Predicting the effects of changes in dissolved input concentration on the variability of discharge concentration at the outlet of the catchment is essential to improve our ability to address the problem of surface water quality. The goal of this study is therefore dedicated to the stochastic quantification of temporal variability of concentration fields in outflow from a catchment system that exhibits linearity and time invariance. A convolution integral is used to determine the output of a linear time-invariant system from knowledge of the input and the transfer function. This work considers that the nonstationary input concentration time series of an inert solute to the catchment system can be characterized completely by the Langevin equation. The closed-form expressions for the variances of inflow and outflow concentrations at the catchment scale are derived using the Fourier–Stieltjes representation approach. The variance is viewed as an index of temporal variability. The closed-form expressions therefore allow to evaluate the impacts of the controlling parameters on the temporal variability of outflow concentration.

Temporal Variability in the Response of a Linear Time-Invariant Catchment System to a Non-Stationary Inflow Concentration Field