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Melt dynamics and glass Topological phases of especially dry and homogenized binary AsxS100-x melts/glasses are examined in Modulated-DSC, Raman scattering and volumetric experiments. In the S-rich glasses (12% 20 as x increases. Taken together, these results underscore that superstrong melts yield isostatically rigid glasses, while fragile ones form either Flexible or Stressed-rigid glasses upon cooling. The onset of the rigidity transition near = 2.22, instead of the usual value of = 2.40, is identified with presence of QT local structures in addition to Pyramidal As(S1/2)3 local structures in the glassy backbone, and with a small but finite fraction of polymeric Sn chains being decoupled from the backbone.

frontiers in materials

Correlating Melt Dynamics and Configurational Entropy Change With Topological Phases of AsxS100–x Glasses and the Crucial Role of Melt/Glass Homogenization