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In this study, a magnetic porphyrin-based porous organic polymer (MP-POP) nanocomposite was successfully synthesized according previous studies and applied as an adsorbent for simultaneous extraction and preconcentration of four neonicotinoid insecticides from surface river water. The MP-POP was characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy/energy dispersive x-ray spectroscopy (SEM/EDS), N 2 -adsorption/desorption analysis, Fourier Transform infrared spectroscopy (FTIR). The neonicotinoid insecticides were quantified using high performance chromatography coupled with diode array detector (HPLC-DAD). The MP-POP shown to have a high surface area, highly porous structure and strong affinity toward the investigated analytes. The adsorption capacities were 99.0, 85.5, 90.0, and 79.4 mg g −1  for acetamiprid, clothiandin, thiacloprid and imidacloprid, respectively. The influential parameters affecting the magmatic μ-solid phase extraction (M-μ-SPE) procedure were investigated using fractional factorial design and surface response methodology (RSM). Under optimum conditions, the method exhibited relatively low limit of detection in the range of 1.3–3.2 ng L −1 , limit of quantification in the range of 4.3–11 ng L −1  and wide linearity (up to 600 μg L −1 ). The intraday and interday precision, expressed as the relative standard deviation (RSD) were <5%. The percentage recoveries for the four target analytes ranged from 91 to 99.3% for the spiked river water samples. The method was applied for determination of neonicotinoids in river water samples and concentrations ranged from 0 to 190 ng L −1 .

frontiers in chemistry

Magnetic Solid Phase Extraction Based on Nanostructured Magnetic Porous Porphyrin Organic Polymer for Simultaneous Extraction and Preconcentration of Neonicotinoid Insecticides From Surface Water