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One Zn-Nd complex [Zn 2 Nd 4 L 2 (OAc) 10 (OH) 2 (CH 3 OH) 2 ] ( 1 ) was synthesized from Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H 2 L).  1  shows nanoscale rectangular structure with sizes of about 0.8 × 1.1 × 2.8 nm.  1  exhibits typical near-infrared luminescence of Nd(III) under the excitation of UV-visible light. Further study shows that the complex displays luminescent response behavior to anions and nitro explosives, especially with high sensitivity to H 2PO2    -and 2,4,6-trinitrophenol.

One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives