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A novel Al 3+  chemosensor  NPA  was designed and synthesized on basis of the mechanism of ICT and CHEF. Upon addition of Al 3+ , the probe  NPA  displayed a bright green fluorescence under UV radiation and visual color change from yellow to colorless. Spectrum titrations showed that  NPA  could be recognized as a fluorescent turn-on probe with 10 −8  M detection level. The probe was successfully applied in real water sample and test paper. More important,  NPA -Al 3+  complex were used as a fluorescent turn-off probe for the detection of ClO −  with the detection as low as 2.34 × 10 −8  M. The performance of  NPA  to Al 3+  and  NPA -Al 3+  complex to ClO −  demonstrated that  NPA  could be served as a sensitive probe and exhibit INHIBIT logic gate behavior with Al 3+  and ClO −  as inputs.

A Naphthalimide-Based Fluorescence “Off-on-Off” Chemosensor for Relay Detection of Al3+ and ClO−