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The new di- and tetranuclear Fe(III) μ-oxido complexes [Fe 4 (μ-O) 4 (PTEBIA) 4 ](CF 3 SO 3 ) 4 (CH 3 CN) 2 ] ( 1a ), [Fe 2 (μ-O)Cl 2 (PTEBIA) 2 ](CF 3 SO 3 ) 2  ( 1b ), and [Fe 2 (μ-O)(HCOO) 2 (PTEBIA) 2 ](ClO 4 ) 2  (MeOH) ( 2 ) were prepared from the sulfur-containing ligand (2-((2,4-dimethylphenyl)thio)-N,N-bis ((1-methyl-benzimidazol-2-yl)methyl)ethanamine (PTEBIA). The tetrairon complex  1a  features four μ-oxido bridges, while in dinuclear  1b , the sulfur moiety of the ligand occupies one of the six coordination sites of each Fe(III) ion with a long Fe-S distance of 2.814(6) Å. In  2 , two Fe(III) centers are bridged by one oxido and two formate units, the latter likely formed by methanol oxidation. Complexes  1a  and  1b  show broad sulfur-to-iron charge transfer bands around 400–430 nm at room temperature, consistent with mononuclear structures featuring Fe-S interactions. In contrast, acetonitrile solutions of  2  display a sulfur-to-iron charge transfer band only at low temperature (228 K) upon addition of H 2 O 2 /CH 3 COOH, with an absorption maximum at 410 nm. Homogeneous oxidative catalytic activity was observed for  1a  and  1b  using H 2 O 2  as oxidant, but with low product selectivity. High valent iron-oxo intermediates could not be detected by UV-vis spectroscopy or ESI mass spectrometry. Rather, evidence suggest preferential ligand oxidation, in line with the relatively low selectivity and catalytic activity observed in the reactions.

Di- and Tetrairon(III) μ-Oxido Complexes of an N3S-Donor Ligand: Catalyst Precursors for Alkene Oxidations