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Hydrogen diffusion and sulfide stress cracking of simulated heat-affected zone (HAZ) of A51665 grade steel were examined using an electrochemical permeation technique, glycerin volumetric method, and constant loading method. HAZ samples were fabricated using a metal thermal cycle simulator with a welding heat input of 20, 35, and 50 kJ/cm. The fractions of bainite and martensite-austenite (M-A) constituent in coarse-grained HAZ (CGHAZ) and intercritical HAZ (ICHAZ) obtained by a simulated thermal cycle with a low heat input (20 kJ/cm) were higher than those with a higher heat input. These fractions contributed to the increase in the reversible hydrogen trap density (N[H]rev) and reversibly trapped hydrogen concentrations (Crev). Although CGHAZ had higher N[H]rev and Crev meaning that it is more likely to be vulnerable to brittle failure by hydrogen, actual fracture by sulfide stress cracking (SSC) occurred in ICHAZ composed of a mixture of soft ferrite/pearlite, and hard bainite and M-A. The hydrogen diffusion/ trapping parameters, which were obtained from the electrochemical permeation or glycerin method, cannot be directly indicative of the resistance to SSC of the steel in a H2S environment. The susceptibility to SSC was more influenced by the level of M-A-localization and localized corrosion attack, acting as a stress intensifier under a tensile load. (Received May 6, 2020; Accepted July 2, 2020)

Study on Hydrogen Diffusion and Sulfide Stress Cracking Behaviors of Simulated Heat-Affected Zone of A516-65 Grade Pressure Vessel Carbon Steel