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We analysed thermal (20°-1000•Ž) phase changes of the substrates of Zn3(PO4)3.2H2O (1) and Mg3(PO4)2.8H20 (7) and their binary mixtures (percentage ratio 10%-90%). Thermal differential analysis (TG, DTG, DTA), IR and XR, showed that the above mentioned substances, heated for 1 hour up to 500•‹ and 1000•Ž changed the structure. Samples contain: 90%, 70%, 50% Zn3(PO4)3-2H2O (1) in the binary mixtures with Mg3(PO4)2.8H2O (7) change the structure at 500•Ž into Zn3(PO4)2 and at 1000•Ž in (ZnMg)3(PO4)2,other binary mixture (30%, 10%) have structure Mg3(PO4)2 (at 1000•Ž).

phosphorus research bulletin

RESEARCH ON INFLUENCE OF TEMPERATURE(20&amp;deg;1000&amp;deg;C) ON BINARY MIXTURES OF SOLID SOLUTIONS OF Zn&lt;SUB&gt;3&lt;/SUB&gt;(PO&lt;SUB&gt;4&lt;/SUB&gt;)&lt;SUB&gt;2&lt;/SUB&gt;.2H&lt;SUB&gt;2&lt;/SUB&gt;O-Mg&lt;SUB&gt;3&lt;/SUB&gt;(PO&lt;SUB&gt;4&lt;/SUB&gt;)&lt;SUB&gt;2&lt;/SUB&gt;. 8H&lt;SUB&gt;2&lt;/SUB&gt;O