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A series of polyimide (PI)-organically modified clay nanocomposites were made to enhance tensile modulus, thermal stability of PI. PI was made from 3, 3', 4, 4'-biphenyl tetracarboxylic dianhydride (BPDA), p-phenylediamine (PDA). Montmorillonite (MMT), one type of layered clay, was treated by dodecylamine salt. XRD indicated that organically modified montmorillonite (OMMT) layers were exfoliated and dispersed into PI-film. Tensile measurements indicated that small amount of OMMT (up to 3%) increased tensile modulus nicely. The glass transition temperatures ( T g ) of the nano-composites are higher than those of pristine PI. Thermal gravimetric analysis (TGA) showed that nanocomposites have higher decomposition temperatures in comparison with the original PI. Keywords: Polyimide; Organically modified clay; Nanocomposites; Dodecylamine. © 2009 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved. DOI: 10.3329/jsr.v1i2.2297

Preparation of Polyimide-Clay Nanocomposites and Their Performance