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Ultrasonic velocities (U), viscosities (η) and densities (ρ) of binary liquid mixtures of di–(2-ethylhexyl) phosphoric acid (DEHPA) with eight non polar diluents viz. n-pentane, n-hexane, n-heptane, benzene, carbon tetrachloride, cyclohexane, carbon disulphide and dioxane are measured at temperature 303.16 K and 0.01MPa for entire range of concentration. The measured data are used to compute acoustic impedance (Z), isentropic compressibility (s), intermolecular free length (Lf), free volume ( Vf ), internal pressure ( i  ) and viscous relaxation time(.). The excess properties are also evaluated from the measured data to study interand intra-molecular interaction between components of liquid mixtures. The research findings may be utilized in solvent extraction process to enhance extraction efficacy.

Acoustic assessment in binary mixtures of a polar nuclear extractant, DEHPA with eight non polar diluents at 303.15K – a comparative study