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Lead alloy electrode which contains noble metals such as silver is used as the anode for cathodic protection in sea water, but the mechanism of formation of the anti-corrosive film is not known as yet. In the previous reports, the author studied stationary polarization curves of lead, silver, etc. with a potentiostat in order to investigate the film formed on the anode in relatively short time. However, for fast electrode reaction in which several kinds of surface films are formed at high velocity, detailed study on the film formation can not be made by the stationary polarization measurement method heretofore in use. Therefore, the potential sweep method was adopted to observe the anodic polarization curves of Pb, Sb and Sn in sodium sulfate and sodium chloride solutions, and the mechanism of formation

Non-Stationary Polarization Curves of Lead, Antimony and Tin in Sodium Chloride and Sodium Sulfate Solutions