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Twenty variously surface-modified mesoporous silica gels were studied as carriers for immobilization by hydrophobic adsorption of the lipases from Rhizomucor miehei (Rm L ) and Thermomyces lanuginosus (Tl L ). Several of the surfacemodified silica gels studied proved to be advantageous supports for Rm L and Tl L resulting in novel biocatalysts of high activity and enantioselectivity in the kinetic resolution of racemic 1-phenylethanol rac-1. The fact that it were different grafting methods which led to the most efficient supports for Rm L and Tl L indicated that the selection of optimal support for the immobilization of a particular lipase cannot be predicted.

Immobilization of lipases from Rhizomucor miehei and Thermomyces lanuginosus by adsorption on variously grafted silica gels