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The Poly(vinylidene fluoride)/CaCu3Ti4O12 (CCTO) nanocrystal composite films(85nm) with relatively high dielectric permittivity (90 at 100Hz) were preparedby the solution casting followed by spin coating technique. The structural, themicrostructural and the dielectric properties of the composites were studiedusing X-ray diffraction, Scanning Electron Microscope, and Impedance analyzerrespectively. The effective dielectric permittivity of the composite increasedwith increase in the volume fraction of CCTO at all the frequencies (100 Hz to1MHz) under investigation. The room temperature dielectric permittivity whichis around 90 at 100Hz, has increased to about 290 at 125oC (100Hz). Theseresults may be exploited in the development of high energy density capacitors.

Dielectric properties of Poly(vinylidene fluoride)/ CaCu3Ti4O12 nanocrystal composite thick films