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The partial and integral enthalpies of mixing of molten, ternary Ag–Cu–Sn alloys were determined at 500, 700 and 900 °C using a Calvet-type microcalorimeter. Five sections in a compositional range from pure Sn to about 40 at.% Sn were investigated. The data were fitted using a Redlich–Kister–Muggiano polynomial, where the binary interaction parameters were taken from the literature. Additionally, the temperature dependence of the ternary interaction parameters was described analytically by a linear function.

Lead-free solder materials: experimental enthalpies of mixing in the Ag–Cu–Sn and Cu–Ni–Sn ternary systems