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Knudsen cell mass spectrometry has been employed to investigate thermodynamically the fcc solid ternary Fe–Ni–Co alloys over the entire range of composition. The “Digital Intensity-Ratio” method has been applied for the determination of the thermodynamic excess properties. The values of the molar excess Gibbs energies  G  E , the molar heats of mixing  H  E , the molar excess entropies  S  E , as well as the thermodynamic activities at 1600 K are presented.

Ternary thermodynamics by computer-aided Knudsen cell mass spectrometry: fcc solid Fe–Ni–Co alloys