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Phase equilibria between the fcc matrix and the hcp nitride phase were installed by long-time heat treatment at 1273 and 1073 K, respectively, in different Fe–Cr–Mn–N alloys. The composition of the phases was determined applying wavelength-dispersive X-ray microanalysis. The results are compared with thermodynamic calculations using published data describing the fcc and the hcp phases in the system Fe–Cr–Mn–N. The agreement is satisfactory at medium concentrations at 1273 K but there are considerable differences at 1073 K.

Nitride Phase Equilibria in the Fe–Cr–Mn–N System at 1273 and 1073 K