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A typical free radical grafting system is composed of a polymer substrate, a vinyl bearing monomer and a free radical initiator (usually a peroxide). When the reaction is to be carried out in a co-rotating twin screw extruder, there are two main ways to feed the chemicals to the extruder: either they are fed together to the main hopper (one-pot feeding) or only the polymer is fed to the main hopper and the grafting monomer and the peroxide are injected downstream either just before or after the first kneading zone (sequential feeding).

Free Radical Grafting of Glycidyl Methacrylate onto PP in a Co-rotating Twin Screw Extruder: Influence of Feeding Mode