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The knowledge of the chain length distribution (CLD) during the operation in a polymerization reactor is necessary in order to control polymer quality. Model-based measurement methods (Kalman filter) provide the possibility of reconstructing on-line not directly accessible process states from easily available measurements. However, the presence of model inaccuracies or disturbances influencing primarily the CLD demand additional measurement information about CLD.

Gel-Permeation Chromatography as a Tool for the Real-Time-Estimation of the Chain length Distribution in a Polymerization Reactor