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A model for the evolution of torque requirements in the batch mixing of silica agglomerates in styrene-butadiene rubber has been developed. The analysis considers the rheology of suspensions as modeled by the Krieger-Dougherty equation but with modifications so that it can apply to a wider range of solids loading, and combines that with a separate model that expresses the kinetics of the dispersion of silica agglomerates. The model shows good agreement with the trends of experimental data, and thus can be used to make predictions about torque requirements for compounding commercial grades of silica into rubber, as related to dispersion, under practical mixing conditions.

Modeling of the Torque Requirements for the Mixing and Dispersion of Silica into Rubber