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In the present study, thin films of Bi 2 S 3  with hollow morphology were deposited by chemical bath deposition at room temperature. The structural, morphological and optical properties of Bi 2 S 3  films were investigated as a function of deposition time. To study the photovoltaic properties, sensitization of SnO 2  photoanode with Bi 2 S 3  was achieved successfully via chemical bath deposition. The solar cell fabricated using SnO 2 –Bi 2 S 3  photoanode showed an open circuit voltage ( V  OC ) of 357 mV, short circuit current density of ( J  SC ) 740.16 μA cm −2  and fill factor  (F.F.)  of 31%.

Time dependent synthesis of crystalline Bi 2 S 3 and its application as a sensitizer in SnO 2 based solar cells