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The enthalpies of mixing in binary liquid alloys of iron with the lanthanides (Pr, Nd, Gd, Tb, Dy and Lu) were determined at 1550–1950 K by means of isoperibolic calorimetry. They show exothermic effects (in the Fe–Pr system partially endothermic) which increase across the lanthanides row from the Fe–Pr system (Δ H  min  = −0.35 ± 0.10 kJ · mol −1  at  x  Pr  = 0.22; Δ H  max  = 0.75 ± 0.24 kJ · mol −1  at  x  Pr  = 0.76;  T  = 1829 K) to the Fe–Lu system (Δ H  min  = −11.58 ± 0.50 kJ · mol −1  at  x  Lu  = 0.35;  T  = 1950 K).

Enthalpies of mixing in liquid alloys of iron with the lanthanides