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Despite its significant technical relevance, a number of uncertainties remain regarding the Fe–Ni–Ti ternary system. These concern phase relations, the solidus–liquidus range and the liquidus projection, especially in the Ti-rich corner. In this study the melting and solidification behaviour of Tirich Fe–Ni–Ti alloys was characterized using differential thermal analysis, electrical conductivity measurements and high-temperature X-ray diffraction. Combining these different methods allowed us to determine the liquidus temperatures more precisely than with differential thermal analysis measurements alone. The results were compared with calculated values using the ThermoCalc software package.

Determination of liquidus temperature in Ti-rich alloys of the Fe–Ni–Ti system obtained by DTA, electrical conductivity and XRD measurements