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In order to define the ability of magnetic elements M = Mn, Fe, Co to stabilise clathrate structures, alloys of the Ba – M – Ge system were investigated in the as-cast state and after annealing at 700°C and 800°C by means of X-ray powder diffraction, light optical and electron-probe microanalysis. Temperatures of phase transformations were derived from differential thermal analysis. Results are summarised in (i) isothermal sections at 700°C and 800°C, (ii) solidus and liquidus surfaces covering the region of existence for both clathrate phases in these systems. Invariant reactions during crystallisation are presented in form of Schultz – Scheil diagrams.

Formation of clathrates Ba–M–Ge(M = Mn, Fe, Co)