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K 2 O introduced with manganese ore is redistributed by evaporation and condensation within submerged arc ferromanganese smelting furnaces. To characterise the phase equilibria relevant to these slags experimental studies have been carried out to determine pseudo-ternary sections of the form “MnO” – CaO – (SiO 2  + Al 2 O 3 ) with a fixed Al 2 O 3 /SiO 2  weight ratio of 0.65 and 6.0 wt.% K 2 O for temperatures in the range 1523 – 1673 K.

Phase equilibria in the system “MnO” – CaO – SiO 2 – Al 2 O 3 – K 2 O relevant to manganese smelting slags