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The isothermal section at 650°C and the vertical section Fe-(Ga 0.75 Al 0.25 ) of the Fe-rich portion in the Fe – Ga – Al ternary system were determined using optical microscopy, scanning electron microscopy, energy dispersion X-ray spectroscopy, X-ray diffraction and differential thermal analysis. The isothermal section of the Fe-rich portion consists of 4 single-phase regions: A2, B2, D0 3 , D0 19 , and 4 two-phase regions: A2 + B2, A2 + D0 3 , D0 3  + D0 19  and B2 + D0 19 . No fcc L1 2  phase region occurs in the isothermal section of the Fe-rich portion. The vertical section Fe-(Ga 0.75 Al 0.25 ) of the Fe-rich portion consists of 3 single-phase regions: A2, B2 and D0 3 , 4 two-phase regions: A2 + D0 3 , D0 3  + D0 19 , A2 + L1 2  and D0 3  + L1 2 , and 2 three-phase regions: D0 3  + D0 19  + L1 2  and A2 + D0 3  + L1 2 .

Phase diagram of the iron-rich portion in the iron–gallium–aluminum ternary system